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By Hassler J.W.

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There is an optimum balance between molecular weight and processability that is defined by the type of mixing equipment used. Increasing the molecular weight distribution at equivalent molecular weight by branching produces more free chain ends and more hysteresis but at moderate levels can improve other properties. Saito [9] showed that in silicon-branched solution SBR, the effect on hysteresis could be minimized and ultimate tensile strength could be improved because of better carbon black dispersion.

International Rubber Conference, Kuala Lumpur, Malaysia, 1975. 21. Subramaniam A. Viscosity of natural rubber. Planters Bull 1984;180:104–112. 22. Kawahara S, Kakubo T, Sakdapipanich JT, Isono Y, Tanaka Y. Characterization of fatty acids linked to natural rubber—Role of linked fatty acids on crystallization of the rubber. Polymer 2000;41:7483–7488. 23. Sharples A. Polymer Crystallization. : Edward Arnold, 1966. Element’s Tech Bull. DPR liquid natural rubber, isolene, kalene, kalar. Belleville, NJ, 2003.

Makromol. , 29/30, 291, 1973. ) Nordsiek [8] expanded the concept of using the glass transition temperature to using the entire damping curve to predict tire performance. 3). The damping curves for an emulsion SBR, a high-vinyl polybutadiene, and a medium-vinyl SBR at the same Tg were compared and shown to be different at temperatures of 20°C–100°C. This led to the proposal of an “integral rubber” that would have a compilation of damping curves from a number of polymers and would incorporate damping behavior that would lead to the “ideal” elastomer for tread compounds.

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